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Effect of Crystallization Temperature on Crystallization and Properties of CaO-Al2O3-MgO-SiO2 Glass-ceramics from Fly Ash and Waste Panel Glass

 LI Baoqing 1,2,3, GUO Yanping 1,2, FANG Hongsheng 1,2, DANG Haifeng 4, HUANG Ling 1, LIANG Zhanxing 5, WANG Wenxiang1,2
(1.Guangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, Guangdong China; 2. Guangdong
Engineering and Technology Research Center of Solid Waste Resource Recovery and Heavy Metal Pollution Control,
Foshan 528216, Guangdong China; 3.South China Normal University, Guangzhou 510631, Guangdong China; 4. School
of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, Guangdong China;
5. Guangzhou Environmental Protection Technology and Equipment Company, Guangzhou, Guangdong China 510091)

Abstract: Glass-ceramics with the pyroxene, forsterite and mullite as the crystalline phases were prepared using fly ash, waste panel glass and chemical reagents by melting method. Effect of crystallization temperature (940 °C-1060 °C) on the crystal performance and microstructure of glass-ceramic samples was analyzed by means of differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscope (SEM). The properties of density, water absorption, flexural strength and micro hardness were also measured. The results showed that the glass-ceramics with the highest bulk density (2.81 g/cm3), highest flexural strength (83.78 MPa), highest micro hardness (7.4 GPa) and the minimum water absorption (0.10%) were obtained by crystallizing at 1030 °C.

Key words: glass-ceramics; crystallization temperature; fly ash; crystallization behavior

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