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Effects of Substitution of Sm2o3 by Pr2O3 on the Structure & Dielectric Properties of Cao- Li2o- Sm2o3- Tio2 Ceramics

HU Dongli1 , ZENG Lingke1 , LIU Pingan1 , SHUI Anzhe1 , WANG Hui1 , LIU Yanchun1 , LI Qian2

(1.Material Ins titute,South China Univers ity of Technology ,Guangzhou 510640)

(2.Henan Univers ity of Science and Technology,Luoyang 471003)

Abstract: In this article,Pr2O3 was used to subs titute Sm2O3to improve the dielectric properties of CaO- Li2O- Sm2O3- TiO2 (CLST) .The ceramics was obtained by solid phase method .It was found that the CLPST- x ceramics exis ted a s ingle perovskite phase . It was showed that the ceramics of CLPST- x have well dielectric properties of higher dielectric cons tant ( εr=101);a lower dielectric los s ( tanδ=0.00923) and low temperature coefficient of the resonant frequency (τf=- 85ppm/℃) when CaO : Li2O :Sm2O3:Pr2O3:TiO2 =16:9:8:4:63 and the s intering temperature is 1300℃. Further more,the crys tal grain is fine in s zeand the grain boundary is clear in the SEM picture.

Keywords: microwave dielectric ceramics ,dielectric properties,CLST,subs titution


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